Information about Vinyl
A vinyl compound is any organic compound that contains a vinyl group (also called ethenyl), −CH=CH2. These are derivatives of ethylene, CH2=CH2, with one hydrogen atom substituted with some other group.
A related phrase is vinylidene which stands for the vinyl residue in an organic compound for instance in 1,1-dichloroethene.
The vinyl group forms part of the allyl group and is also contained in all acrylates. Many alkenes contain a vinyl group.
Because of the covalent bond, vinyls can be made to polymerize, forming vinyl polymers. In these polymers, the double bonds of the vinyl monomers turn into single bonds and the different monomers are joined by single bonds. This is an instance of addition polymerization. There are no vinyl groups in the resulting polymer. It is also important to ascertain the absence of unreacted vinyl monomer in the final product when the monomer is toxic or reduces the performance of the plastic.
Polymers
- Main article: Vinyl polymer
- Polyvinyl chloride (PVC) is made by polymerization of the monomer vinyl chloride (chloroethene) CH2=CHCl
- Polyvinyl acetate (PVAc) is made by polymerization of vinyl acetate. In a water suspension, this is used as a glue.
- Polyvinyl alcohol (PVA) is produced by hydrolysis of polyvinyl acetate. (Not by polymerization of the monomer vinyl alcohol or ethenol, which is an unfavored keto-enol tautomer of acetaldehyde.)
Etymology
The etymology of vinyl is the Latin vinum = "wine", because of its relationship with alcohol (in its original sense of ethyl alcohol). organic compounds]] An organic compound is any member of a large class of chemical compounds whose molecules contain carbon; for historical reasons discussed below, a few types of compounds such as carbonates, carbon oxides and cyanides, as well as elemental carbon are
..... Click the link for more information.
..... Click the link for more information.
4, 2
(mildly acidic oxide)
Electronegativity 2.55 (Pauling scale)
Ionization energies
(more) 1st: 1086.5 kJmol−1
2nd: 2352.6 kJmol−1
3rd: 4620.5 kJmol−1
Atomic radius 70 pm
Atomic radius (calc.
..... Click the link for more information.
(mildly acidic oxide)
Electronegativity 2.55 (Pauling scale)
Ionization energies
(more) 1st: 1086.5 kJmol−1
2nd: 2352.6 kJmol−1
3rd: 4620.5 kJmol−1
Atomic radius 70 pm
Atomic radius (calc.
..... Click the link for more information.
1, −1
(amphoteric oxide)
Electronegativity 2.20 (Pauling scale) More
Atomic radius 25 pm
Atomic radius (calc.) 53 pm
Covalent radius 37 pm
Van der Waals radius 120 pm
Miscellaneous
Thermal conductivity (300 K) 180.
..... Click the link for more information.
(amphoteric oxide)
Electronegativity 2.20 (Pauling scale) More
Atomic radius 25 pm
Atomic radius (calc.) 53 pm
Covalent radius 37 pm
Van der Waals radius 120 pm
Miscellaneous
Thermal conductivity (300 K) 180.
..... Click the link for more information.
Covalent bonding is a form of chemical bonding that is characterized by the sharing of pairs of electrons between atoms, or between atoms and other covalent bonds.
..... Click the link for more information.
..... Click the link for more information.
Ethylene (or IUPAC name ethene) is the chemical compound with the formula C2H4. It is the simplest alkene. Because it contains a double bond, ethylene is called an unsaturated hydrocarbon or an olefin.
..... Click the link for more information.
..... Click the link for more information.
1, −1
(amphoteric oxide)
Electronegativity 2.20 (Pauling scale) More
Atomic radius 25 pm
Atomic radius (calc.) 53 pm
Covalent radius 37 pm
Van der Waals radius 120 pm
Miscellaneous
Thermal conductivity (300 K) 180.
..... Click the link for more information.
(amphoteric oxide)
Electronegativity 2.20 (Pauling scale) More
Atomic radius 25 pm
Atomic radius (calc.) 53 pm
Covalent radius 37 pm
Van der Waals radius 120 pm
Miscellaneous
Thermal conductivity (300 K) 180.
..... Click the link for more information.
1,1-Dichloroethene, commonly called 1,1-dichloroethylene or 1,1-DCE, is an organochloride with the molecular formula C2H2Cl2. It is a highly flammable, colorless liquid with a sharp, harsh odor.
..... Click the link for more information.
..... Click the link for more information.
An allyl group is an alkene hydrocarbon group with the formula H2C=CH-CH2-. It is made up of a vinyl group, CH2=CH-, attached to a methylene -CH2. For example allyl alcohol has the structure H2C=CH-CH2OH .
..... Click the link for more information.
..... Click the link for more information.
The acrylate ion (CH2=CHCOO−) is the ion of acrylic acid. Acrylates are the salts and esters of acrylic acid. They are also known as propenoates (since acrylic acid is also known as 2-propenoic acid).
..... Click the link for more information.
..... Click the link for more information.
alkene, olefin, or olefine is an unsaturated chemical compound containing at least one carbon-to-carbon double bond. The simplest alkenes, with only one double bond and no other functional groups, form a homologous series of hydrocarbons with the general formula
..... Click the link for more information.
..... Click the link for more information.
Covalent bonding is a form of chemical bonding that is characterized by the sharing of pairs of electrons between atoms, or between atoms and other covalent bonds.
..... Click the link for more information.
..... Click the link for more information.
alkene polymerisation, in which each Styrene monomer unit's double bond reforms as a single bond with another styrene monomer and forms polystyrene.]] In polymer chemistry, polymerization
..... Click the link for more information.
..... Click the link for more information.
Vinyl polymers are a group of polymers derived from vinyl monomers. Their backbone is an extended alkane chain, made by polymerizing an alkene group (C=C) into a chain (..-C-C-C-C-..). In popular usage, "vinyl" refers only to PVC.
..... Click the link for more information.
..... Click the link for more information.
A monomer (from Greek mono "one" and meros "part") is a small molecule that may become chemically bonded to other monomers to form a polymer.
Examples of monomers are hydrocarbons such as the alkene and arene homologous series.
..... Click the link for more information.
Examples of monomers are hydrocarbons such as the alkene and arene homologous series.
..... Click the link for more information.
Addition polymerisation, also called polyaddition or chain growth polymerization, is a polymerisation technique where unsaturated monomer molecules add on to a growing polymer chain one at a time.
..... Click the link for more information.
..... Click the link for more information.
Vinyl polymers are a group of polymers derived from vinyl monomers. Their backbone is an extended alkane chain, made by polymerizing an alkene group (C=C) into a chain (..-C-C-C-C-..). In popular usage, "vinyl" refers only to PVC.
..... Click the link for more information.
..... Click the link for more information.
Polyvinyl chloride, (IUPAC Polychloroethene) commonly abbreviated PVC, is a widely used thermoplastic polymer. In terms of revenue generated, it is one of the most valuable products of the chemical industry. Globally, over 50% of PVC manufactured is used in construction.
..... Click the link for more information.
..... Click the link for more information.
alkene polymerisation, in which each Styrene monomer unit's double bond reforms as a single bond with another styrene monomer and forms polystyrene.]] In polymer chemistry, polymerization
..... Click the link for more information.
..... Click the link for more information.
A monomer (from Greek mono "one" and meros "part") is a small molecule that may become chemically bonded to other monomers to form a polymer.
Examples of monomers are hydrocarbons such as the alkene and arene homologous series.
..... Click the link for more information.
Examples of monomers are hydrocarbons such as the alkene and arene homologous series.
..... Click the link for more information.
Vinyl chloride monomer (VCM), also known as chloroethene in IUPAC nomenclature, is an important industrial chemical chiefly used to produce its polymer, polyvinyl chloride (PVC). At room temperature, VCM is a toxic, colorless gas with a sickly sweet odor.
..... Click the link for more information.
..... Click the link for more information.
Polyvinyl acetate (PVA or PVAc) is a rubbery synthetic polymer. It is prepared by polymerization of vinyl acetate monomer, also referred to as VAM. Partial or complete hydrolysis of the polymer is used to prepare polyvinyl alcohol.
..... Click the link for more information.
..... Click the link for more information.
Vinyl acetate, also known as VAM for vinyl acetate monomer, has the chemical formula CH3COOCH=CH2 and is a colorless liquid with a sweet flavor. Systematic names include 1-acetoxyethylene and acetic acid ethenyl ester.
..... Click the link for more information.
..... Click the link for more information.
Polyvinyl alcohol (PVOH, PVA, or PVAL) is a water-soluble synthetic polymer.
..... Click the link for more information.
Properties
Polyvinyl alcohol has excellent film forming, emulsifying, and adhesive properties. It is also resistant to oil, grease and solvent...... Click the link for more information.
- :Not to be confused with electrolysis
Hydrolysis is a chemical reaction or process in which a chemical compound is broken down by reaction with water.[1][2] This is the type of reaction that is used to break down polymers.
..... Click the link for more information.
Polyvinyl acetate (PVA or PVAc) is a rubbery synthetic polymer. It is prepared by polymerization of vinyl acetate monomer, also referred to as VAM. Partial or complete hydrolysis of the polymer is used to prepare polyvinyl alcohol.
..... Click the link for more information.
..... Click the link for more information.
Ethenol, also called vinyl alcohol, hydroxyethene or hydroxyethylene, is an alcohol with chemical formula C2H4O (H2C=CHOH) and CAS number 557-75-5. Normally it exists as the tautomer acetaldehyde.
..... Click the link for more information.
..... Click the link for more information.
Tautomers are organic compounds that are interconvertible by a chemical reaction called tautomerization. As most commonly encountered, this reaction results in the formal migration of a hydrogen atom or proton, accompanied by a switch of a single bond and adjacent
..... Click the link for more information.
..... Click the link for more information.
Acetaldehyde, sometimes known as ethanal, is an organic chemical compound with the formula CH3CHO or MeCHO. It is a flammable liquid with a fruity smell.
..... Click the link for more information.
..... Click the link for more information.
Etymology is the study of the history of words - when they entered a language, from what source, and how their form and meaning have changed over time.
In languages with a long written history, etymology makes use of philology, the study of how words change from culture to
..... Click the link for more information.
In languages with a long written history, etymology makes use of philology, the study of how words change from culture to
..... Click the link for more information.
Latin}}}
Official status
Official language of: Vatican City
Used for official purposes, but not spoken in everyday speech
Regulated by: Opus Fundatum Latinitas
Roman Catholic Church
Language codes
ISO 639-1: la
ISO 639-2: lat
..... Click the link for more information.
Official status
Official language of: Vatican City
Used for official purposes, but not spoken in everyday speech
Regulated by: Opus Fundatum Latinitas
Roman Catholic Church
Language codes
ISO 639-1: la
ISO 639-2: lat
..... Click the link for more information.
This article is copied from an article on Wikipedia.org - the free encyclopedia created and edited by online user community. The text was not checked or edited by anyone on our staff. Although the vast majority of the wikipedia encyclopedia articles provide accurate and timely information please do not assume the accuracy of any particular article. This article is distributed under the terms of GNU Free Documentation License.
Herod_Archelaus