Information about Hazardous Waste
- For the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal, see Basel Convention.
Put simply, a hazardous waste is waste that poses substantial or potential threats to public health or the environment and generally exhibits one or more of these characteristics:
- ignitable (i.e. flammable)
- oxidizing
- corrosivity
- toxic
- radioactive
- eco-toxic
- cause, or significantly contribute to an increase in mortality (death) or an increase in serious irreversible, or incapacitating reversible illness; or
- pose a substantial present or potential hazard to human health or the environemnt when improperly treated, stored, transported, or disposed of, or otherwise managed.
Regulatory history
Resource Conservation and Recovery Act (RCRA)
Modern hazardous waste regulations in the U.S. began with the Resource Conservation and Recovery Act (RCRA) which was enacted in 1976. The primary contribution of RCRA was to create a "cradle to grave" system of record keeping for hazardous wastes. Hazardous wastes must be tracked from the time they are generated until the time they are ultimately disposed or recycled.RCRA's record keeping system helps to track the lifecycle of hazardous waste and reduces the amount of hazardous waste illegally disposed. Regulators can monitor hazardous waste by following the 'trail' of the waste as is transferred from one entity to another from the time it is generated until it is disposed.
Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA)
The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), was enacted in 1980. The primary contribution of CERCLA was to create a "Superfund" and provided for the clean-up and remediation of closed and abandoned hazardous waste sites.Hazardous wastes in the United States
Many types of businesses generate hazardous waste. Some are small companies that may be located in a community. For example, dry cleaners, automobile repair shops, hospitals, exterminators, and photo processing centers all generate hazardous waste. Some hazardous waste generators are larger companies like chemical manufacturers, electroplating companies, and oil refineries.A US facility that treats, stores or disposes of hazardous waste must obtain a permit for doing so under the Resource Conservation and Recovery Act. Generators of and transporters of hazardous waste must meet specific requirements for handling, managing, and tracking waste. Through the RCRA, Congress directed the United States Environmental Protection Agency to create regulations to manage hazardous waste. Under this mandate, the EPA developed strict requirements for all aspects of hazardous waste management including the treatment, storage, and disposal of hazardous waste. In addition to these federal requirements, states may develop more stringent requirements or requirements that are broader in scope than the federal regulations.
In the United States, hazardous wastes generated by commercial or industrial activities may be classified as "listed" hazardous wastes or "characteristic" hazardous wastes by the EPA.
In regulatory terms, a Resource Conservation and Recovery Act (RCRA) hazardous waste is a waste that either:
- Appears on one of the four hazardous wastes lists (F-list, K-list, P-list, or U-list), or
- Exhibits at least one of the four "characteristics" of hazardous waste (ignitability, corrosivity, reactivity, or toxicity)
Listed wastes
Listed hazardous wastes are generated by specific industries and processes and are automatically considered hazardous waste based solely on the process that generates them and irrespective of whether a test of the waste shows any of the "characteristics" of hazardous waste. Examples of listed wastes include:- many sludges leftover from electroplating processes.
- certain waste from iron and steel manufacturing
- wastes from certain cleaning and/or degreasing processes
- The F-list (non-specific source wastes). This list identifies wastes from common manufacturing and industrial processes, such as solvents that have been used in cleaning or degreasing operations. Because the processes producing these wastes can occur in different sectors of industry, the F-listed wastes are known as wastes from non-specific sources.
- The K-list (source-specific wastes). This list includes certain wastes from specific industries, such as petroleum refining or pesticide manufacturing. Certain sludges and wastewaters from treatment and production processes in these industries are examples of source-specific wastes.
- Discarded Wastes: P-List and U-List wastes are actually sublists of the same major list applying to discarded wastes. These wastes apply to commercial chemical products that are considered hazardous when discarded and are regulated under the following U.S. Federal Regulation: 40 C.F.R. 261.33(e) and 261.33(f). P-List wastes are wastes that are considered "acutely hazardous" when discarded and are subject to more stringent regulation. Nitric oxide is an example of a P-list waste and carries the number P076. U-Listed wastes are considered "hazardous" when discarded and are regulated in a somewhat less stringent manner than P-Listed wastes.
Toxicity Characteristic Leaching Procedure (TCLP)
Toxicity of a hazardous waste is defined through a laboratory procedure called the Toxicity Characteristic Leaching Procedure (TCLP). The TCLP helps identify wastes likely to leach concentrations of contaminants that may be harmful to human health or the environment.Universal wastes
Universal wastes are hazardous wastes that (in the U.S.):- generally pose a lower threat relative to other hazardous wastes
- are ubiquitous and produced in very large quantities by a large number of generators.
Universal wastes are subject to somewhat less sringent regulatory requirements and small quantity generators of universal wastes may be classified as "conditionally-exempt small quantity generators" (CESQGs) which releases them from some of the regulatory requirements for the handling and storage hazardous wastes.
Universal wastes must still be disposed of properly. (For more information, see Fact Sheet: Conditionally Exempt Small Quantity Generator)
Other hazardous wastes
The U.S. Environmental Protection Agency has other ways of regulating hazardous waste. These "rules" include:- The "Mixture Rule" - 40 CFR Section 261-23 applies to a mixture of a listed hazardous waste and a solid waste and states that the result of a mixture of these two wastes is regulated as a hazardous waste. Exemptions may apply in some cases.
- The "Derived-from Rule" - 40 CFR Section 261.3(b) applies to a waste that is generated from the treatment, storage or disposal of a hazardous waste (for example, the ash from the incineration of hazardous waste). Wastes "derived" in this manner may be regulated as hazardous wastes.
- The "Contained-in Rule" - - 40 CFR Section 261.3(f) applies to soil, groundwater, surface water and debris that are contaminated with a listed hazardous waste.
Exempted hazardous wastes
USEPA regulations automatically exempt certain solid wastes from being regulated as "hazardous wastes". Important: This does not necessarily mean the wastes are not hazardous nor that they are not regulated. An exempted hazardous waste simply means that the waste is not regulated by the primary hazardous waste regulations. Many of these wastes may by regulated by different statutes and/or regulations and/or by different regulatory agencies. "Exempted" hazardous wastes include:- Household hazardous waste (HHW); (see below)
- Agricultural wastes which are returned to the ground as fertilizer;
- Mining overburden returned to the mine site;
- Utility wastes from [coal] combustion to produce electricity;
- Oil and natural gas exploration drilling waste;
- Wastes from the extraction of beneficiation, and processing of ores and minerals, including coal;
- Cement kiln wastes;
- Wood treated with arsenic preservatives.
- Certain chromium-containing wastes (See Code of Federal Regulations Section 261.4(b))
- Recycled hazardous wastes: Some hazardous wastes that are recycled may also be exempted from hazardous waste regulations.
Household Hazardous Waste
Household Hazardous Waste (HHW) (also referred to as domestic hazardous waste) is waste that is generated from residential households. HHW only applies to wastes that are the result of the use of materials that are labeled for and sold for "home use".The following list includs categories often applied to HHW. It is important to note that many of these categories overlap and that many houshold wastes can fall into multiple categories:
- Paints and solvents
- Automotive wastes (used motor oil, antifreeze, etc.)
- Pesticides (insecticides, herbicides, fungicides, etc.)
- Mercury-containing wastes (thermometers, switches, fluorescent lighting, etc)
- Electronics (computers, televisions, cell phones)
- Aerosols / Propane cylinders
- Caustics / Cleaning agents
- Refrigerant-containing appliances
- Batteries
- Ammunition
- Radioactive waste (some home smoke detectors are classified as radioactive waste because they contain very small amounts of a radioactive isotope of americium (see: Disposing of Smoke Detectors).
Modern landfills are designed to handle normal amounts of HHW and minimize the environmental impacts. However, there are still going to be some impacts and there are many ways that homeowners can keep these wastes out of landfills. Contact the US EPA ( USEPA Household Hazardous Wastes for tips on how to safely dispose of HHW.
Laws regulating HHW in the U.S. are gradually becoming more strict. As of 2007, radioactive smoke detectors are the only HHW that are managed nationally. While it is still legal in the United States to dispose of smoke detectors in your trash in most places, manufacturers of smoke detectors must accept returned units for disposal as mandated by the Nuclear Regulatory law 10 CFR 32.27. If you send your detector back to a manufacturer then it will be disposed in a nuclear waste facility.
In the U.S., states are regulating various HHW waste disposal in MSW landfills on a state by state basis. Some commonly regulated wastes in some (but not all) states include restrictions on the disposal of:
- Recyclables (especially "source-separated" recyclables or recyclables that have already been separated from solid waste). In this case this would only apply to household hazardous wastes that have been separated for recycling.
- Lead-acid batteries
- Mercury-containing wastes
- Rechargeable batteries
- Cathode ray tubes (CRTs) from older computer monitors and televisions
- Cell phones and computers
- Refrigerant containing appliances such as a refrigerator, air conditioner or dehumidifier.
Local solid waste authorities and health deparments may also have specific bans on wastes that apply to their service area.
Solid Waste Haulers and HHW - One "catch-22" that residents often encounter is that while it may be legal to dispose of some HHW in their regular trash, the waste hauler that collects the trash can choose not to haul the waste. It is not uncommon for a waste hauler to refuse to pick up municipal solid waste that contains things like paint and fluorescent light bulbs. There is often little recourse for residents in this case. In these cases the resident may have to make their own arrangements to dispose of the waste by taking it directly to a landfill or solid waste transfer station.
See also
- List of waste management companies
- List of waste management topics
- List of solid waste treatment technologies
- List of Superfund sites in the United States
- List of topics dealing with environmental issues
- Pollution
- Remediation
- Radioactive waste
- Recycling
- Superfund
- Toxic waste
- Waste types
External links
- The Household Chemical Encyclopedia - Over 100 Potential Sources of Household Hazardous Wastes
- Agency for Toxic Substances and Disease Registry
- The EPA's hazardous waste page
- The U.S. EPA's Hazardous Waste Cleanup Information System
- What Did We Know About Hazardous Waste and When Did We Know It, a February 2002 essay by William Sanjour
Inflammability is the ease with which a substance will ignite, causing fire or combustion. Materials that will ignite at temperatures commonly encountered are considered inflammable, with various specific definitions giving a temperature requirement.
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Redox (shorthand for reduction/oxidation reaction) describes all chemical reactions in which atoms have their oxidation number (oxidation state) changed.
This can be either a simple redox process such as the oxidation of carbon to yield carbon dioxide, or the
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This can be either a simple redox process such as the oxidation of carbon to yield carbon dioxide, or the
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A corrosive substance is one that will destroy or irreversibly damage a substance, including living tissue, by chemical action (rapid corrosion of living tissue). The main hazards to people include damage to eyes, skin and tissue under the skin, but inhalation or ingestion of a
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Toxicity is the degree to which something is able to produce illness or damage to an exposed organism. Toxicity can refer to the effect on a whole organism, such as a human or a bacterium or a plant, or to a substructure, such as a cell (cytotoxicity) or an organ (organotoxicity
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Radioactive decay is the process in which an unstable atomic nucleus loses energy by emitting radiation in the form of particles or electromagnetic waves. This decay, or loss of energy, results in an atom of one type, called the parent nuclide
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The Resource Conservation and Recovery Act (RCRA), enacted in 1976, is a Federal law of the United States contained in 42 U.S.C. §§6901-6992k. It is usually pronounced as "rick-rah" or "Wreck-rah.
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Death is the permanent end of the life of a biological organism. Death may refer to the end of life as either an event or condition.[1] Many factors can cause or contribute to an organism's death, including predation, disease, habitat destruction, senescence,
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The Resource Conservation and Recovery Act (RCRA), enacted in 1976, is a Federal law of the United States contained in 42 U.S.C. §§6901-6992k. It is usually pronounced as "rick-rah" or "Wreck-rah.
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Superfund is the common name for the United States environmental law officially known as the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA
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Superfund is the common name for the United States environmental law officially known as the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA
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Dry cleaning is any cleaning process for clothing and textiles using an organic solvent rather than water — generally known as dry cleaning fluid, and typically this is tetrachloroethylene (called perchloroethylene or perc in the industry).
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automobile (from Greek auto, self and Latin mobile moving, a vehicle that moves itself rather than being moved by another vehicle or animal) or motor car (usually shortened to just car) is a wheeled passenger vehicle that carries its own motor.
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pest is an organism which has characteristics that are regarded as injurious or unwanted. This is most often because it causes damage to agriculture through feeding on crops or parasitising livestock, such as codling moth on apples, or boll weevil on cotton.
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Manufacturing (from Latin manu factura, "making by hand") is the use of tools and labor to make things for use or sale. The term may refer to a vast range of human activity, from handicraft to high tech, but is most commonly applied to industrial production, in which raw
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Electroplating is the process of using electrical current to coat an electrically conductive object with a relatively thin layer of metal. The primary application of electroplating deposits a layer of a metal having some desired property (e.g.
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oil refinery is an industrial process plant where crude oil is processed and refined into more useful petroleum products, such as gasoline, diesel fuel, asphalt base, heating oil, kerosene, and liquefied petroleum gas.
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The Resource Conservation and Recovery Act (RCRA), enacted in 1976, is a Federal law of the United States contained in 42 U.S.C. §§6901-6992k. It is usually pronounced as "rick-rah" or "Wreck-rah.
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Environmental Protection Agency
EPA
Environmental Protection Agency logo
Agency overview
Formed December 2, 1970
Employees 17,964 (2005) [1]
Annual Budget $7.
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EPA
Environmental Protection Agency logo
Agency overview
Formed December 2, 1970
Employees 17,964 (2005) [1]
Annual Budget $7.
..... Click the link for more information.
Environmental Protection Agency
EPA
Environmental Protection Agency logo
Agency overview
Formed December 2, 1970
Employees 17,964 (2005) [1]
Annual Budget $7.
..... Click the link for more information.
EPA
Environmental Protection Agency logo
Agency overview
Formed December 2, 1970
Employees 17,964 (2005) [1]
Annual Budget $7.
..... Click the link for more information.
Electroplating is the process of using electrical current to coat an electrically conductive object with a relatively thin layer of metal. The primary application of electroplating deposits a layer of a metal having some desired property (e.g.
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Nitric oxide or Nitrogen monoxide is a chemical compound with chemical formula NO. This gas is an important signaling molecule in the body of mammals including humans and is an extremely important intermediate in the chemical industry.
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Fluorescence is a luminescence that is mostly found as an optical phenomenon in cold bodies, in which the molecular absorption of a photon triggers the emission of another photon with a longer wavelength.
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battery is a device consisting of one or more electrochemical cells, which store chemical energy and make it available in an electrical form. There are many types of electrochemical cells, including galvanic cells, electrolytic cells, fuel cells, flow cells, and voltaic cells.
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1. Electron guns 2. Electron beams 3. Focusing coils 4. Deflection coils 5. Anode connection 6. Mask for separating beams for red, green, and blue part of displayed image 7.
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Municipal solid waste (MSW) is a waste type that includes predominantly household waste (domestic waste) with sometimes the addition of commercial wastes collected by a municipality within a given area.
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ore is a volume of rock containing components or minerals in a mode of occurrence that renders it valuable for mining. An ore must contain materials that are
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- valuable
- in concentrations that can be profitably mined, transported, milled, and processed.
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A mineral is a naturally occurring substance formed through geological processes that has a characteristic chemical composition, a highly ordered atomic structure and specific physical properties.
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Coal (IPA: /ˈkəʊl/) is a fossil fuel formed in swamp ecosystems where plant remains were saved by water and mud from oxidization and biodegradation.
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Cement kilns are used for the pyroprocessing stage of manufacture of Portland and other types of hydraulic cement, in which calcium carbonate reacts with silica-bearing minerals to form a mixture of calcium silicates.
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3, 5
(mildly acidic oxide)
Electronegativity 2.18 (scale Pauling)
Ionization energies
(more) 1st: 947.0 kJmol−1
2nd: 1798 kJmol−1
3rd: 2735 kJmol−1
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(mildly acidic oxide)
Electronegativity 2.18 (scale Pauling)
Ionization energies
(more) 1st: 947.0 kJmol−1
2nd: 1798 kJmol−1
3rd: 2735 kJmol−1
..... Click the link for more information.
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